In Starlight Shores, I'd say Isaac Chuck (hope I got the name right), he's one of 3 brothers and wears sunglasses. The only decently good looking sim in Starlight Shores. However, my sim did not find him attractive.
My sim, who I've used in numerous games, is head over heals about Matthew Hamming. Using a mod, she can gage her attraction and to her he is 'blindingly stunning', his reaction is the same. However, the dude is old. She knows the young again potion, and whenever she gives it to him (numerous games), he wants to break up! Guess she'll have to stay married to an old geezer this time and find another one later.